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    Early life[ edit ] Lewis was born in and raised in Weymouth, Massachusettswhere there exists a street named for him, G.

    Lewis Way, off Summer Street. Additionally, the wing of the new Weymouth High School Chemistry department has been named in his honor. Lewis received his primary education at home from his parents, Frank Wesley Lewis, a lawyer of independent character, and Mary Burr White Lewis.

    He read at age three and was intellectually precocious. In his family moved to Lincoln, Nebraskaand in he received his first formal education at the university preparatory school. Inafter two years at the University of NebraskaLewis transferred to Harvard Universitywhere he obtained his B. After a year of teaching at Phillips Academy in AndoverLewis returned to Harvard to study with the physical chemist T.

    Richards and obtained his Ph. In the following years, Lewis started to criticize and denounce his former teacher on many occasions, calling Nernst's work on his heat theorem "a regrettable episode in the history of chemistry". There is evidence that he used the Nobel nominating and reporting procedures to block a Nobel Prize for Lewis in thermodynamics by nominating Lewis for the prize three times, and then using his position as a committee member to write negative reports.

    He was appointed instructor in thermodynamics and electrochemistry. The next year he returned to Cambridge, Massachusetts when the Massachusetts Institute of Technology MIT appointed him to a faculty position, in which he had a chance to join a group of outstanding physical chemists under the direction of Arthur Amos Noyes.

    He became an assistant professor inassociate professor inand full professor in Lewis Hall at Berkeley, built inis named in his honor. The most important was thermodynamics, a subject in which Richards was very active at that time. Although most of the important thermodynamic relations were known bythey were seen as isolated equations, and had not yet been rationalized as a logical system, from which, given one relation, the rest could be derived.

    Moreover, these relations were inexact, applying only to ideal chemical systems. These were two outstanding problems of theoretical thermodynamics. In two long and ambitious theoretical papers in andLewis tried to provide a solution. Lewis introduced the thermodynamic concept of activity and coined the term " fugacity ". Lewis believed that fugacity was the fundamental principle from which a system of real thermodynamic relations could be derived.

    This hope was not realized, though fugacity did find a lasting place in the description of real gases. These ideas were well known to physicists and mathematicians, but not to most practical chemists, who regarded them as abstruse and inapplicable to chemical systems. Heat of reaction is not, of course, a measure of the tendency of chemical changes to occur, and Lewis realized that only free energy and entropy could provide an exact chemical thermodynamics. He derived free energy from fugacity; he tried, without success, to obtain an exact expression for the entropy function, which in had not been defined at low temperatures.

    Richards too tried and failed, and not until Nernst succeeded in was it possible to calculate entropies unambiguously. At Harvard, Lewis also wrote a theoretical paper on the thermodynamics of blackbody radiation in which he postulated that light has a pressure. He later revealed that he had been discouraged from pursuing this idea by his older, more conservative colleagues, who were unaware that Wilhelm Wien and others were successfully pursuing the same line of thought.

    From the start of his career, Lewis regarded himself as both chemist and physicist. Valence theory[ edit ] Lewis' cubical atoms as drawn in About Lewis started to use unpublished drawings of cubical atoms in his lecture notes, in which the corners of the cube represented possible electron positions. Lewis later cited these notes in his classic paper on chemical bonding, as being the first expression of his ideas.

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    Inwhile trying to explain the laws of valence to his students, Lewis conceived the idea that atoms were built up of a concentric series of cubes with electrons at each corner. Lewis did not publish his theory of the cubic atom, but in it became an important part of his theory of the shared electron pair bond. Inhe published his classic paper on chemical bonding "The Atom and the Molecule" [11] in which he formulated the idea of what would become known as the covalent bondconsisting of a shared pair of electrons, and he defined the term odd molecule the modern term is free radical when an electron is not shared.

    He included what became known as Lewis dot structures as well as the cubical atom model. These ideas on chemical bonding were expanded upon by Irving Langmuir and became the inspiration for the studies on the nature of the chemical bond by Linus Pauling. Relativity[ edit ] In he published the first of several papers on relativityin which he derived the mass - energy relationship in a different way from Albert Einstein 's derivation. Tolman combined his methods with special relativity.

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    He resigned inrefusing to state the cause for his resignation; it has been speculated that it was due to a dispute over the internal politics of that institution or to the failure of those he had nominated to be elected. His decision to resign may have been sparked by resentment over the award of the Nobel Prize for chemistry to his student, Harold Ureyfor the discovery of deuteriuma prize Lewis almost certainly felt he should have shared for his work on purification and characterization of heavy water.

    Lewis acids and bases Inhe formulated the electron-pair theory of acid—base reactions. In this theory of acids and basesa "Lewis acid" is an electron-pair acceptor and a "Lewis base" is an electron-pair donor. This year he also published a monograph on his theories of the chemical bond [17] Based on work by J. Willard Gibbsit was known that chemical reactions proceeded to an equilibrium determined by the free energy of the substances taking part.

    Lewis spent 25 years determining free energies of various substances. In he and Merle Randall published the results of this study, [18] which helped formalize modern chemical thermodynamics. Heavy water[ edit ] Lewis was the first to produce a pure sample of deuterium oxide heavy water in [19] and the first to study survival and growth of life forms in heavy water. Lawrence's cyclotronhe was able to study many of the properties of atomic nuclei.

    Seaborgwho was retained for post-doctoral work as Lewis' personal research assistant. Seaborg went on to win the Nobel Prize in Chemistry and have the element seaborgium named in his honor while he was still alive.

    Other achievements[ edit ] InLewis was the first to propose an empirical equation describing the failure of strong electrolytes to obey the law of mass actiona problem that had perplexed physical chemists for twenty years. Inby studying the magnetic properties of solutions of oxygen in liquid nitrogenhe found that O4 molecules were formed.

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    Inhe coined the term " photon " for the smallest unit of radiant energy light. Actually, the outcome of his letter [23] to Nature was not what he had intended. In the letter, he proposed a photon being a structural element, not energy. He insisted on the need for a new variable, the number of photons. Although his theory differed from the quantum theory of light introduced by Albert Einstein inhis name was adopted for what Einstein had called a light quantum Lichtquant in German.

    Later years[ edit ] Over the course of his career, Lewis published on many other subjects besides those mentioned in this entry, ranging from the nature of light quanta to the economics of price stabilization. In the last years of his life, Lewis and graduate student Michael Kashahis last research associate, established that phosphorescence of organic molecules involves emission of light from one electron in an excited triplet state a state in which two electrons have their spin vectors oriented in the same direction, but in different orbitals and measured the paramagnetism of this triplet state.

    Lewis had been working on an experiment with liquid hydrogen cyanideand deadly fumes from a broken line had leaked into the laboratory. The coroner ruled that the cause of death was coronary artery diseasebecause of a lack of any signs of cyanosis, [25] but some believe that it may have been a suicide. If Lewis's death was indeed a suicide, a possible explanation was depression brought on by a lunch with Irving Langmuir. Langmuir and Lewis had a long rivalry, dating back to Langmuir's extensions of Lewis's theory of the chemical bond.

    Langmuir had been awarded the Nobel Prize in chemistry for his work on surface chemistrywhile Lewis had not received the Prize despite having been nominated 41 times.

    An hour later, he was found dead. Langmuir's papers at the Library of Congress confirm that he had been on the Berkeley campus that day to receive an honorary degree. They had two sons, both of whom became chemistry professors, and a daughter.
    John, thank you so much for joining the show.

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    Thank you for having me. Great so, let's just jump straight in here. If you could give a quick overview of what FetLife is from your perspective. I mean, the really easiest way to explain it to somebody is Facebook for the kinky community. So, a lot of the features you'll find on Facebook or what Facebook does as social network, it's really just like a niche social network.

    Great, great so, in terms of fetish or the fetish community I try not to use the word fetish anymore. I've slowly been moving towards using the word kinky or kink.

    I don't look down on anybody who does use it. It just, sometimes for some people the word fetish invokes like, "Oh, this person must be sick because they have a fetish. So to me, they're more like kinks, things that turn you on.

    You bring up a good point. It's just that I'm as familiar with the language as you in that a fetish isn't the best name for this kind of stuff. When I'm thinking about it, it does kind of have a negative derogatory sense. Like people start to think of I don't know, guys wearing Pampers and more extreme stuff should we say and not the norm. So when you say kink, would you say that's the more acceptable word and that's the more common word used for this kind of stuff today or is kind of the cool word?

    Like, "That's what the cool. I wish I knew what the cool kids did. I don't know what the hipsters call it but, I tend to use the word kinky just because it just doesn't bring negative connotations but, it is all encompassing. It's just when I think fetish, I think of you know, if you watch TV shows like some of these documentaries like They make love to their car and they have to do it 16 times a day" and they bring a psychologist in to try to help this person. By using the word kink, we're trying to remove that that the person needs to it as opposed to like, this is something that they really just enjoy doing.

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    Cool, cool, very cool. So, we were just talking a second ago about why this came into being for you and I felt that was very important the point you made.

    So, why did you bring FetLife into the world? What do you think it's serving in terms of people's needs? I couldn't tell you what needs that it serves but, I know why I started it because, for each person it's different.

    So, why I started it was because I never wanted anybody to feel uncomfortable with who they were sexually. I felt very uncomfortable about who I was sexually my whole life. I really don't think I'll ever get over it nor to be honest, do I ever want to get over it. I'm afraid if I do get over it that my desire to keep on pushing FetLife forward will disappear. Not to get too personal but, it's kind of like happiness. I'm not big into happiness for myself because, not being happy drives me more than being happy.

    As soon as I'm happy, I can sit on the coach on watch TV all day. When I'm not happy, I can work all day. So, too much happiness is not a good thing at least for me. I know what drives me. I know what works for me. So yes, FetLife was just a culmination of my whole life's story. My father was a famous hair stylist. I grew up in his hair salon. It was the largest hair salon in Montreal at the time and the majority of his friends and co-workers were gay.

    This was the 80s. I was 10 years old. I was very curious. I was listening to their stories, listening to them talk and from listening to their stories of not feeling normal from my own stories of feeling alone and feeling like, "Oh my God.

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    Something must be screwed up because, I come from a traditional Greek background where you respect and love the woman. It didn't make sense in my head even if two consensual people wanted to do it but in my head, I was the only person at the age of 12, 13, 14 years old who ever would want these things.

    When I was that age, it was even before the internet. I think I had a baud modem and I was connecting to BVSs back in the day to try to download you know asky games. So, the resources weren't there and then as I got older, I went into IRC and then it's like, "Oh my God, there's other people just like me here. I was like, "Wow Who wanted to take advantage?

    I was looking at www. So, they were like the leading alternative dating site on the internet, their own friend finder and I joined the site and I didn't feel better with who I was.

    I just felt like, "Ah, there's something wrong with me and these people are taking advantage of me. They're taking advantage of people with kinks. They're not making people feel good about who they are. It was more like they were exploiting in a niche, a market rather than So, I guess it was a paid service? Yeah, it still is a paid service. If there's other people on the site Alright so, it's always good to hear people's stories which you've just given us because, as for me, I've often commented on the podcast myself, it's like I kind of had to hit bottom in this area before I took action.

    So, it's also interesting that you said like happiness doesn't often motivate you. It's like the other stuff that motivates you, gets you going, gets you working and I guess that's where FetLife came from. It was obviously your frustration, your loneliness. How did the vision come to you like one day or was there a particular event where you, you know maybe you had to leave a girlfriend or something that you kind of really hit bottom. I'm not saying this to rub it in but, often people on this podcast, they're listening and sometimes they're not in good places and they don't realize that it's a powerful to hit bottom.

    I have a bunch of stories like that. So non-chronological order or any specific order but, a year after I started FetLife, I almost closed FetLife because, I was dating a girl. I was in love. Her father I guess didn't know what I did or definitely didn't know what I did. He was a very prominent member at a very, very high position and they found out what I did for a living and basically said, "You have 24 hours to kick John out of the house or we'll disown you and never speak to you again.

    I was living in Nova Scotia at the time, drove back to Montreal. I guess it's 16 hours away and I was like, "What the hell am I doing? Is this going to be like this?

    So, you never spoke to her again? So, she never contacted you and you never contacted her? I tried contacting her. I tried to make it work but, it was basically, "Don't talk to me. I don't know the full story and this guy was legit and he wasn't like my father saying, "Oh, I'm mad at you," but he's not really mad.

    It was like, "Yeah, I'm really going to disown you. I was working at FetLife full time. I came back to Montreal. I got a part time job as a director of user experience at a startup. My boss at the time, he was I think I'm just going to close the site. I think that it's going to cause me too much trouble in my life.

    I think I'll just do something else. How many users, members did it have at that time, roughly? Probably a ,At that time, what was No, no it wasn't getting any negative press. It was very, very positive. It was very positive and my boss at the time, he took me out for coffee and he's like, "Let me tell you a story of my father and maybe this will help you.

    My dad was doing the right thing and it's all that matters. He explained to me what he was doing and why he was doing it. People's perceptions change and as long as people know why you're doing it and if you're doing it for all the right reasons, your family will still love you and the people who matter will still stay in your life.

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